Dr. C. T. Chanter and his colleagues have published a paper on the unresolved quantitative discrepancies between experimental and theoretical Cu Kα spectra. For more information, see the paper, "Theoretical Determination of Characteristic X-Ray Lines and the Copper Kα Spectrum", C. T. Chantler et al., Phys. Rev. Lett. 103, 123002 (2009).
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